A Large‐Bandgap Conjugated Polymer for Versatile Photovoltaic Applications with High Performance

A new copolymer PM6 based on fluorothienyl-substituted benzodithiophene is synthesized and characterized. The inverted polymer solar cells based on PM6 exhibit excellent performance with Voc of 0.98 V and power conversion efficiency (PCE) of 9.2% for a thin-film thickness of 75 nm. Furthermore, the single-junction semitransparent device shows a high PCE of 5.7%. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.…

• UD
  U.S. Department of Energy
• BE
  Basic Energy Sciences
• DO
  Division of Materials Sciences and Engineering