articleGeophysical Journal InternationalJan 31, 2011BRONZE OA

Thermodynamics of mantle minerals - II. Phase equilibria

University College London

Indexed incrossrefdoaj

Abstract

P>We complete the development and description of a thermodynamic method for the computation of phase equilibria and physical properties of multiphase mantle assemblages. Our previous paper focused on the computation of physical properties. In this paper, our focus shifts to the phase equilibria. We further develop our theory to specify the ideal and excess contributions to solution properties and derive properties of multiphase assemblages. We discuss our global inversion strategy for determining the values of the free parameters in our theory and compare inverted parameter values with expectations based on scaling arguments. Comparisons between our method and experimental phase equilibria data encompass…

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637
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Authors

2

Topics & keywords

Keywords
  • Mantle (geology)
  • Computation
  • Statistical physics
  • Scaling
  • Minification
  • Gibbs free energy
  • Thermodynamics
  • Geophysics
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