articleJournal of the American Chemical SocietySep 23, 2009Closed access

Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes

RTRyō TanakaMYMakoto YamashitaKNKyoko Nozaki

The University of Tokyo

PubMed
Indexed incrossrefpubmed

Abstract

Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3,500,000 and a turnover frequency of 150,000 h(-1), both of which are the highest values reported to date.

Citation impact

888
total citations
FWCI
22.50
Percentile
100%
References
38
Citations per year

Authors

3

Topics & keywords

Topics
Keywords
  • Chemistry
  • Catalysis
  • Potassium hydroxide
  • Pincer movement
  • Carbon dioxide
  • Iridium
  • Formate
  • Turnover number
UN Sustainable Development Goals
  • Clean water and sanitation
No related works found for this paper.

Funding