Mass spectrometry of oligosaccharides
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Abstract
Abstract I. Introduction 162 II. CHARACTERISTICS OF TANDEM MASS SPECTRA OF CARBOHYDRATES 163 A. Ionization of Carbohydrates 163 1. Electrospray Ionization (ESI) 163 2. Matrix‐Assisted Laser Desorption/Ionization (MALDI) 163 B. Nomenclature for the Fragmentation of Glycoconjugates 164 C. Tandem MS of Native Oligosaccharide Molecular Ions 165 1. Protonated Ions 165 2. Deprotonated Ions 166 3. Alkali and Alkaline Earth Adducted Ions 166 D. Tandem MS of Permethylated and Peracetylated Oligosaccharides 169 E. Tandem MS of Reductively Aminated Carbohydrates 170 F. Discrimination of Monosaccharide Linkages 171 G. Gas‐Phase Degradation of Oligosaccharides 178 H. Computer‐Based Approaches for Interpretation of…
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1Topics & keywords
Topics
Keywords
- Chemistry
- Oligosaccharide
- Tandem mass spectrometry
- Mass spectrometry
- Chromatography
- Protein mass spectrometry
- Electrospray ionization
- Chemical ionization
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