articleJournal of the American Chemical SocietyMar 12, 2015Closed access

Metallic Nickel Nitride Nanosheets Realizing Enhanced Electrochemical Water Oxidation

University of Science and Technology of China · Collaborative Innovation Center of Chemistry for Energy Materials · +2 more institutions

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Abstract

Exploring efficient and inexpensive oxygen evolution reaction (OER) electrocatalysts is of great importance for various electrochemical energy storage and conversion technologies. Ni-based electrocatalysts have been actively pursued because of their promising activity and earth abundance. However, the OER efficiency for most of the developed Ni-based electrocatalysts has been intrinsically limited due to their low electrical conductivity and poor active site exposure yield. Herein, we report metallic Ni3N nanosheets as an efficient OER electrocatalyst for the first time. The first-principles calculations and electrical transport property measurements unravel that the Ni3N is intrinsically metallic, and the…

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