articleJournal of the American Chemical SocietyMay 17, 2005Closed access

GaN:ZnO Solid Solution as a Photocatalyst for Visible-Light-Driven Overall Water Splitting

Kurashiki University of Science and the Arts · The University of Tokyo · +2 more institutions

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Abstract

Photocatalytic overall water splitting has been studied extensively from the viewpoint of solar energy conversion. Despite numerous attempts, none have yielded satisfactory results for the development of photocatalysts, which work under visible light irradiation to efficiently utilize solar energy. We report here the first example of visible-light-driven overall water splitting on a novel oxynitride photocatalyst, a solid solution of GaN and ZnO with a band gap of 2.58-2.76 eV, modified with RuO2 nanoparticles. In contrast to the conventional non-oxide photocatalysts, such as CdS, the solid solution is stable during the overall water splitting reaction. This is the first example of achieving overall water…

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