reviewBeilstein Journal of NanotechnologyJan 16, 2014DIAMOND OA

Design criteria for stable Pt/C fuel cell catalysts

Max-Planck-Institut für Nachhaltige Materialien · Max-Planck-Institut für Kohlenforschung

PubMed
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Abstract

Platinum and Pt alloy nanoparticles supported on carbon are the state of the art electrocatalysts in proton exchange membrane fuel cells. To develop a better understanding on how material design can influence the degradation processes on the nanoscale, three specific Pt/C catalysts with different structural characteristics were investigated in depth: a conventional Pt/Vulcan catalyst with a particle size of 3-4 nm and two Pt@HGS catalysts with different particle size, 1-2 nm and 3-4 nm. Specifically, Pt@HGS corresponds to platinum nanoparticles incorporated and confined within the pore structure of the nanostructured carbon support, i.e., hollow graphitic spheres (HGS). All three materials are characterized by…

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