Size- and Shape-Controlled Magnetic (Cr, Mn, Fe, Co, Ni) Oxide Nanocrystals via a Simple and General Approach

A general, reproducible, and simple strategy using generic chemicals is introduced for controlling the size, shape, and size distribution of oxide nanocrystals. The reaction system was generally composed of the metal fatty acid salts, the corresponding fatty acids, and a hydrocarbon solvent. The method is based on the pyrolysis of metal fatty acid salts, the most common metal compounds compatible with nonaqueous solutions. Synthesis of nearly monodisperse Fe3O4 nanocrystals in a large size range (3−50 nm) was developed as the model system. The method was further applied for the growth of oxide nanocrystals of the other magnetic metals in the fourth rowCr2O3, MnO, Co3O4, and NiO nanocrystals. The size and shape…