articleChemistry of MaterialsMay 1, 2006Closed access

Evolution of Surface Functional Groups in a Series of Progressively Oxidized Graphite Oxides

University of Szeged · Hungarian Academy of Sciences · +1 more institution

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Abstract

This study contributes to the sustained effort to unravel the chemical structure of graphite oxide (GO) by proposing a model based on elemental analysis, transmission electron microscopy, X-ray diffraction, 13C magic-angle spinning NMR, diffuse reflectance infrared Fourier transform spectroscopy, X-ray photoelectron spectroscopy, and electron spin resonance investigations. The model exhibits a carbon network consisting of two kinds of regions (of trans linked cyclohexane chairs and ribbons of flat hexagons with CC double bonds) and functional groups such as tertiary OH, 1,3-ether, ketone, quinone, and phenol (aromatic diol). The latter species give clear explanation for the observed planar acidity of GO, which…

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