articleAdvanced MaterialsJan 14, 2009Closed access

Conjugated Microporous Polymers

AIAndrew I. Cooper

University of Liverpool

Indexed incrossref

Abstract

Abstract Conjugated microporous polymers are of great interest because they have potential to combine high surface areas in the dry state with physical properties relevant to organic electronics. A series of recent reports has shown that materials such as poly(aryleneethynylene)s (PAEs), poly(phenyl‐ene butadiynylene)s, poly(phenylene vinylene), poly( p ‐phenylene)s, polysilanes, polyanilines, and polytriazines can be produced as microporous networks with apparent Brunauer–Emmett–Teller surface areas of more than 1000 m 2 g −1 in some cases. Micropore size and surface area can be synthetically fine tuned in amorphous PAE polymers and copolymers, something which was previously thought to be the preserve of…

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Topics & keywords

Topics
Keywords
  • Conjugated microporous polymer
  • Materials science
  • Microporous material
  • Polymer
  • Conjugated system
  • Amorphous solid
  • Phenylene
  • Nanotechnology
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