Two-Step Relaxation in a Linear Tetranuclear Dysprosium(III) Aggregate Showing Single-Molecule Magnet Behavior
Institute of Chemistry · Changchun Institute of Applied Chemistry · +2 more institutions
Abstract
A well-defined two-step relaxation, described by the sum of two modified Debye functions, is observed in a new alkoxido-bridged linear tetranuclear Dy(III) aggregate showing single-molecule magnet behavior with a remarkably large energy barrier. This compound represents a model molecular aggregate with a clear two-step relaxation evidenced by frequency-dependent susceptibility, which therefore may stimulate further investigations regarding the relaxation dynamics of lanthanide-based systems.
Citation impact
- FWCI
- 23.25
- Percentile
- 100%
- References
- 30
Authors
8- YGYun‐Nan GuoCorresponding
Institute of Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Leiden University
- GXGong‐Feng Xu
Changchun Institute of Applied Chemistry, Institute of Chemistry, Chinese Academy of Sciences, Leiden University
- PGPatrick Gámez
Changchun Institute of Applied Chemistry, Institute of Chemistry, Leiden University, Chinese Academy of Sciences
- LZLang Zhao
Leiden University, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Institute of Chemistry
- SLShuang‐Yan Lin
Leiden University, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Institute of Chemistry
Topics & keywords
- Chemistry
- Dysprosium
- Lanthanide
- Relaxation (psychology)
- Single-molecule magnet
- Debye
- Magnet
- Aggregate (composite)
- Affordable and clean energy