reviewChemical ReviewsFeb 21, 2014HYBRID OA

Two-Dimensional Zeolites: Current Status and Perspectives

Jagiellonian University · Czech Academy of Sciences, J. Heyrovský Institute of Physical Chemistry · +2 more institutions

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Abstract

Zeolites are well-known as valuable crystalline solids with framework structures containing discrete micropores of molecular dimensions that accommodate exchangeable extraframework cation sites.1−3 In terms of host−guest interactions, zeolites can be viewed as host frameworks with structurally intact and immutable three-dimensional (3D) structures. They show exceptional catalytic and sorption characteristics together with very desirable environmental qualities.4−7 Zeolites are widely used in commercial applications as catalysts for hydrocarbon conversions in petroleum and chemical industries, 8−10 as sorbents for small-molecule separation processes, and as ion exchangers in detergents.11

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