articleJournal of the American Chemical SocietyMar 3, 2014GREEN OA

Water Adsorption in Porous Metal–Organic Frameworks and Related Materials

Kavli Energy NanoScience Institute · Lawrence Berkeley National Laboratory · +3 more institutions

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Abstract

Water adsorption in porous materials is important for many applications such as dehumidification, thermal batteries, and delivery of drinking water in remote areas. In this study, we have identified three criteria for achieving high performing porous materials for water adsorption. These criteria deal with condensation pressure of water in the pores, uptake capacity, and recyclability and water stability of the material. In search of an excellently performing porous material, we have studied and compared the water adsorption properties of 23 materials, 20 of which are metal-organic frameworks (MOFs). Among the MOFs are 10 zirconium(IV) MOFs with a subset of these, MOF-801-SC (single crystal form), -802, -805,…

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