Stable Superhydrophobic Coatings from Polyelectrolyte Multilayers

The present study demonstrates that the superhydrophobic behavior of the lotus leaf structure can be mimicked by creating a honeycomb-like polyelectrolyte multilayer surface overcoated with silica nanoparticles. Superhydrophobicity was achieved by coating this highly textured multilayer surface with a semifluorinated silane. The surface maintains its superhydrophobic character even after extended immersion in water. The key structural elements needed to create stable, superhydrophobic coatings from polyelectrolyte multilayers are discussed.