Fluctuation theorems: Work is not an observable
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Abstract
The characteristic function of the work performed by an external time-dependent force on a Hamiltonian quantum system is identified with the time-ordered correlation function of the exponentiated system's Hamiltonian. A similar expression is obtained for the averaged exponential work which is related to the free energy difference of equilibrium systems by the Jarzynski work theorem.
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Topics
Keywords
- Observable
- Hamiltonian (control theory)
- Fluctuation theorem
- Exponential function
- Work (physics)
- Quantum
- Hamiltonian system
- Statistical physics
UN Sustainable Development Goals
- Affordable and clean energy
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