articleNature CommunicationsApr 2, 2015GOLD OA

Pseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors

The University of Tokyo · National Institute of Advanced Industrial Science and Technology · +2 more institutions

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Abstract

High-power Na-ion batteries have tremendous potential in various large-scale applications. However, conventional charge storage through ion intercalation or double-layer formation cannot satisfy the requirements of such applications owing to the slow kinetics of ion intercalation and the small capacitance of the double layer. The present work demonstrates that the pseudocapacitance of the nanosheet compound MXene Ti2C achieves a higher specific capacity relative to double-layer capacitor electrodes and a higher rate capability relative to ion intercalation electrodes. By utilizing the pseudocapacitance as a negative electrode, the prototype Na-ion full cell consisting of an alluaudite Na2Fe2(SO4)3 positive…

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Authors

8

Topics & keywords

Keywords
  • Pseudocapacitance
  • Materials science
  • Supercapacitor
  • Electrode
  • Nanosheet
  • Capacitance
  • Intercalation (chemistry)
  • Electrochemistry
UN Sustainable Development Goals
  • Affordable and clean energy
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