articleOrganic LettersJul 11, 2011Closed access

Eosin Y Catalyzed Visible Light Oxidative C–C and C–P bond Formation

DPDurga Prasad HariBKBurkhard König

University of Regensburg

PubMed
Indexed incrossrefpubmed

Abstract

Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.

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Authors

2

Topics & keywords

Topics
Keywords
  • Eosin Y
  • Chemistry
  • Malononitrile
  • Visible spectrum
  • Catalysis
  • Oxidative phosphorylation
  • Eosin
  • Photochemistry
UN Sustainable Development Goals
  • Clean water and sanitation
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