Plasmons in nearly touching metallic nanoparticles: singular response in the limit of touching dimers

The response of gold nanoparticle dimers is studied theoretically near and beyond the limit where the particles are touching. As the particles approach each other, a dominant dipole feature is observed that is pushed into the infrared due to interparticle coupling and that is associated with a large pileup of induced charge in the interparticle gap. The redshift becomes singular as the particle separation decreases. The response weakens for very small separation when the coupling across the interparticle gap becomes so strong that dipolar oscillations across the pair are inhibited. Lowerwavelength, higher-order modes show a similar separation dependence in nearly touching dimers. After touching, singular…