articleJournal of the American Chemical SocietyJan 21, 2009Closed access

Polymer Semiconductors for Artificial Photosynthesis: Hydrogen Evolution by Mesoporous Graphitic Carbon Nitride with Visible Light

Max Planck Institute of Colloids and Interfaces · Fuzhou University · +1 more institution

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Abstract

We investigated semiconductor characteristics for polymeric carbon nitride as a metal-free photocatalyst working with visible light and have shown that the efficiency of hydrogen production by photochemical water reduction can be improved by approximately 1 order of magnitude by introducing the right type of mesoporosity into polymeric C(3)N(4). We anticipate a wide rang of potential application of C(3)N(4) as energy transducers for artificial photosynthesis in general, especially with a 3D continuous nanoarchitecture. Moreover, the results of finding photoactivity for carbon nitride nanoparticles can enrich the discussion on prebiotic chemistry of the Earth, as HCN polymer clusters are unequivocal in the…

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