articleNano LettersDec 22, 2014GREEN OA

Graphene Quantum Dots Coated VO 2 Arrays for Highly Durable Electrodes for Li and Na Ion Batteries

Nanyang Technological University · China Jiliang University

PubMed
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Abstract

Nanoscale surface engineering is playing important role in enhancing the performance of battery electrode. VO2 is one of high-capacity but less-stable materials and has been used mostly in the form of powders for Li-ion battery cathode with mediocre performance. In this work, we design a new type of binder-free cathode by bottom-up growth of biface VO2 arrays directly on a graphene network for both high-performance Li-ion and Na-ion battery cathodes. More importantly, graphene quantum dots (GQDs) are coated onto the VO2 surfaces as a highly efficient surface "sensitizer" and protection to further boost the electrochemical properties. The integrated electrodes deliver a Na storage capacity of 306 mAh/g at 100…

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