articleNano LettersAug 25, 2007Closed access

Temperature Dependence of the Raman Spectra of Graphene and Graphene Multilayers

University of California, Riverside

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Abstract

We investigated the temperature dependence of the frequency of G peak in the Raman spectra of graphene on Si/SiO2 substrates. The micro-Raman spectroscopy was carried out under the 488 nm laser excitation over the temperature range from -190 to +100 degrees C. The extracted value of the temperature coefficient of G mode of graphene is chi = -0.016 cm-1/ degrees C for the single layer and chi = -0.015 cm-1/ degrees C for the bilayer. The obtained results shed light on the anharmonic properties of graphene.

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Authors

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Topics & keywords

Keywords
  • Graphene
  • Raman spectroscopy
  • Materials science
  • Anharmonicity
  • Bilayer graphene
  • Atmospheric temperature range
  • Analytical Chemistry (journal)
  • Spectral line
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