articleJournal of the American Chemical SocietyApr 10, 2015Closed access

Mesoporous N-Doped Carbons Prepared with Thermally Removable Nanoparticle Templates: An Efficient Electrocatalyst for Oxygen Reduction Reaction

South China University of Technology · Energy Research Institute · +1 more institution

PubMed
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Abstract

Thermally removable nanoparticle templates were used for the fabrication of self-supported N-doped mesoporous carbons with a trace amount of Fe (Fe-N/C). Experimentally Fe-N/C was prepared by pyrolysis of poly(2-fluoroaniline) (P2FANI) containing a number of FeO(OH) nanorods that were prepared by a one-pot hydrothermal synthesis and homogeneously distributed within the polymer matrix. The FeO(OH) nanocrystals acted as rigid templates to prevent the collapse of P2FANI during the carbonization process, where a mesoporous skeleton was formed with a medium surface area of about 400 m(2)/g. Subsequent thermal treatments at elevated temperatures led to the decomposition and evaporation of the FeO(OH) nanocrystals…

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