Porous, Fluorescent, Covalent Triazine‐Based Frameworks Via Room‐Temperature and Microwave‐Assisted Synthesis

Porous, fluorescent, covalent triazine-based frameworks (CTFs) are obtained in an unprecedentedly mild reaction, opening up a scalable pathway for molecular building blocks previously thought incompatible with this chemistry. Choice of monomers and synthetic conditions determines the optical properties and nano-scale ordering of these highly microporous materials with BET surface areas exceeding 1100 m2 g−1 and exceptional CO2 capacities (up to 4.17 mmol g−1). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not…

• RS
  Royal Society
• EA
  Engineering and Physical Sciences Research Council

  Award: EP/H000925/1