articleJournal of the American Chemical SocietyJan 12, 2008Closed access

A Plasmonic Photocatalyst Consisting of Silver Nanoparticles Embedded in Titanium Dioxide

The University of Tokyo · Friedrich Schiller University Jena · +2 more institutions

PubMed
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Abstract

Titanium dioxide (TiO2) displays photocatalytic behavior under near-ultraviolet (UV) illumination. In another scientific field, it is well understood that the excitation of localized plasmon polaritons on the surface of silver (Ag) nanoparticles (NPs) causes a tremendous increase of the near-field amplitude at well-defined wavelengths in the near UV. The exact resonance wavelength depends on the shape and the dielectric environment of the NPs. We expected that the photocatalytic behavior of TiO2 would be greatly boosted if it gets assisted by the enhanced near-field amplitudes of localized surface plasmon (LSP). Here we show that this is true indeed. We named this new phenomenon "plasmonic photocatalysis". The…

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