reviewChemical ReviewsJan 17, 2012Closed access

Hofmeister Phenomena: An Update on Ion Specificity in Biology

University of Florence

PubMed
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Abstract

CONTENTS\n1. Introduction—The Background to Hofmeister Effects\n1.1. A Caveat on Language: Progress in Theory\n1.2. Why Hofmeister Matters in Biology\n1.3. Hofmeister Series\n2. Molecular Interactions\n2.1. Backdrop of Classical Theoretical Ideas\n2.2. Interplay between Different Forces\n3. Specific Ion Effects in the Physical Chemistry of\nAqueous Solutions\n3.1. Viscosity\n3.2. Activity Coefficients\n3.3. pH and Buffers\n4. Correlations with Physico-Chemical Parameters:\nThe Law of Matching Water Affinities\n5. Hofmeister Effects in the Bulk Phase\n6. Hofmeister Effects in Surfactant and Polymer\nSystems and at Interfaces\n7. Hofmeister Effects in Proteins and Enzymes\n7.1. Proteins\n7.2. Enzymes\n8.…

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