articleJournal of the American Chemical SocietyMar 14, 2014Closed access

CoSe 2 Nanoparticles Grown on Carbon Fiber Paper: An Efficient and Stable Electrocatalyst for Hydrogen Evolution Reaction

Beijing University of Chemical Technology · SLAC National Accelerator Laboratory

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Abstract

Development of a non-noble-metal hydrogen-producing catalyst is essential to the development of solar water-splitting devices. Improving both the activity and the stability of the catalyst remains a key challenge. In this Communication, we describe a two-step reaction for preparing three-dimensional electrodes composed of CoSe2 nanoparticles grown on carbon fiber paper. The electrode exhibits excellent catalytic activity for a hydrogen evolution reaction in an acidic electrolyte (100 mA/cm(2) at an overpotential of ∼180 mV). Stability tests though long-term potential cycles and extended electrolysis confirm the exceptional durability of the catalyst. This development offers an attractive catalyst material for…

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1,382
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Authors

4

Topics & keywords

Keywords
  • Overpotential
  • Electrocatalyst
  • Catalysis
  • Chemistry
  • Electrolysis of water
  • Water splitting
  • Electrolysis
  • Electrolyte
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