Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47
Centre National de la Recherche Scientifique · Institut Lavoisier de Versailles · +2 more institutions
Abstract
A distinct step in the isotherm occurs during the adsorption of CO2 on MIL-53 at 304 K. Such behavior is neither observed during the adsorption of CH4 on MIL-53 nor during the adsorption on the isostructural MIL-47. This phenomenon seems to be due to a different mechanism than that of previous adsorption steps on MOF samples. It is suggested that a breathing behavior is induced in MIL-53 during CO2 adsorption.
Citation impact
- FWCI
- 19.01
- Percentile
- 100%
- References
- 26
Authors
6- SBSandrine BourrellyCorresponding
Centre National de la Recherche Scientifique, Institut Lavoisier de Versailles, Université de Versailles Saint-Quentin-en-Yvelines, Institut Universitaire de France
- PLPhilip L. Llewellyn
Université de Versailles Saint-Quentin-en-Yvelines, Centre National de la Recherche Scientifique, Institut Universitaire de France, Institut Lavoisier de Versailles
- CSChristian Serre
Institut Universitaire de France, Centre National de la Recherche Scientifique, Institut Lavoisier de Versailles, Université de Versailles Saint-Quentin-en-Yvelines
- FMFranck Millange
Université de Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles, Centre National de la Recherche Scientifique, Institut Universitaire de France
- TLThierry Loiseau
Institut Universitaire de France, Université de Versailles Saint-Quentin-en-Yvelines, Centre National de la Recherche Scientifique, Institut Lavoisier de Versailles
Topics & keywords
- Isostructural
- Chemistry
- Adsorption
- Methane
- Nanoporous
- Metal-organic framework
- Carbon dioxide
- Inorganic chemistry
- Clean water and sanitation