Hf isotope ratio analysis using multi-collector inductively coupled plasma mass spectrometry: an evaluation of isobaric interference corrections

From measurements of Hf–Yb mixtures, we have found that the correction of isobaric interferences involving accepted Yb isotope ratios and reasonable estimates of mass bias result in a significantly under-corrected 176Hf, which is proportional to the amount of Yb added. This can be explained by (1) a significant difference in the instrumental mass bias between Hf and Yb, and (2) that the accepted values for isotopic ratios within the Yb and/or Hf systems are incorrect. We have evaluated these possibilities by measuring mixed solutions of Yb and Hf on two MC-ICP-MS instruments and undertaking a series of REE fractionation experiments using a thermal ionisation mass spectrometer (TIMS). Our results indicate that…