articleAngewandte Chemie International EditionMar 2, 2011Closed access

Tuning the Basicity of Ionic Liquids for Equimolar CO 2 Capture

Oak Ridge National Laboratory · Zhejiang University of Technology · +2 more institutions

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Abstract

What a catch! Basic ionic liquids (ILs) based on a phosphonium hydroxide derivative can be tuned for CO2 capture by varying the weak proton donors, which have different pKa values. The stability, absorption capacity, and absorption enthalpy of the ILs could be easily tuned: the best IL for CO2 capture has good stability (>300 °C), energy saving (ca. 56 kJ mol−1), and equimolar absorption capability.

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Authors

6

Topics & keywords

Keywords
  • Phosphonium
  • Ionic liquid
  • Absorption (acoustics)
  • Chemistry
  • Enthalpy
  • Proton
  • Hydroxide
  • Ionic bonding
UN Sustainable Development Goals
  • Affordable and clean energy
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