A Facile Band Alignment of Polymeric Carbon Nitride Semiconductors to Construct Isotype Heterojunctions

Junction function: All-organic isotype heterojunctions are formed through the band alignment of polymeric carbon nitride semiconductors (CN and CNS, see scheme), improving the efficiency of charge separation and prolonging the lifetime of charge carriers. These polymeric heterostructures demonstrate an excellent performance for heterogeneous photocatalysis, as shown in a hydrogen-generation assay. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting…