Assembly of Metal–Organic Frameworks (MOFs) Based on Indium‐Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage
Jilin University · State Key Laboratory of Inorganic Synthesis and Preparative Chemistry · +5 more institutions
Abstract
The key to soc-cess: The trimer building block [In3O(CO2)6] and a tetracarboxylate organic linker assemble into a novel porous metal–organic framework (see picture; In green, C gray, N blue, O red; cavity: yellow sphere) having an unprecedented soc topology (soc=square–octahedron) and high H2 uptake. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z604306_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Citation impact
- FWCI
- 32.40
- Percentile
- 100%
- References
- 58
Authors
7- YLYunling Liu
Jilin University, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, University of South Florida
- JFJarrod F. Eubank
University of South Florida
- ACAmy Cairns
University of South Florida
- JEJuergen Eckert
University of California, Santa Barbara, Los Alamos National Laboratory
- VKVictor Kravtsov
Institute of Applied Physics, Academy of Sciences of Moldova, University of South Florida
Topics & keywords
- Trimer
- Metal-organic framework
- Topology (electrical circuits)
- Indium
- Block (permutation group theory)
- Hydrogen storage
- Linker
- Octahedron