articleChemical CommunicationsJan 1, 2015HYBRID OA

Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity

Christian-Albrechts-Universität zu Kiel · Institute of Inorganic Chemistry of the Slovak Academy of Sciences · +10 more institutions

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Abstract

A series of nine Ce(iv)-based metal organic frameworks with the UiO-66 structure containing linker molecules of different sizes and functionalities were obtained under mild synthesis conditions and short reaction times. Thermal and chemical stabilities were determined and a Ce-UiO-66-BDC/TEMPO system was successfully employed for the aerobic oxidation of benzyl alcohol.

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