A Rationally Designed Universal Catalyst for Suzuki–Miyaura Coupling Processes

Unprecedented scope, reactivity, and stability are displayed by a new catalyst system. This was demonstrated with general and efficient syntheses of sterically hindered (hetero)biaryls (see examples shown), mild coupling reactions of alkyl boron derivatives, and rapid coupling reactions of aryl chlorides at room temperature. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z53615_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.