reviewAngewandte Chemie International EditionJun 25, 2009GREEN OA

Palladium(II)‐Catalyzed CH Activation/CC Cross‐Coupling Reactions: Versatility and Practicality

Albany Molecular Research (United States) · Scripps Research Institute

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Abstract

Abstract Pick your Pd partners : A number of catalytic systems have been developed for palladium‐catalyzed CH activation/CC bond formation. Recent studies concerning the palladium(II)‐catalyzed coupling of CH bonds with organometallic reagents through a Pd II /Pd 0 catalytic cycle are discussed (see scheme), and the versatility and practicality of this new mode of catalysis are presented. Unaddressed questions and the potential for development in the field are also addressed. magnified image In the past decade, palladium‐catalyzed CH activation/CC bond‐forming reactions have emerged as promising new catalytic transformations; however, development in this field is still at an early stage compared to the…

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