A Mononuclear Dysprosium Complex Featuring Single‐Molecule‐Magnet Behavior
Beijing National Laboratory for Molecular Sciences · State Key Laboratory of Rare Earth Materials Chemistry and Application · +2 more institutions
Abstract
No dates for Dy3+: With a single-ion magnet containing dysprosium, magnetic-site dilution leads to a hysteresis loop that can be detected at 0.5 and 2 K. On cooling below 8 K, the relaxation mechanism of the undiluted complex changes from a thermally activated process to quantum tunneling. The quantum tunneling can be suppressed by applying a direct-current field and by magnetic site dilution. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information…
Citation impact
- FWCI
- 20.70
- Percentile
- 100%
- References
- 39
Authors
5- SJShang‐Da JiangCorresponding
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Application, Peking University
- BWBing‐Wu Wang
Peking University, State Key Laboratory of Rare Earth Materials Chemistry and Application, Beijing National Laboratory for Molecular Sciences
- GSGang Su
University of Chinese Academy of Sciences
- ZWZhe‐Ming Wang
State Key Laboratory of Rare Earth Materials Chemistry and Application, Peking University, Beijing National Laboratory for Molecular Sciences
- SGSong Gao
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Application, Peking University
Topics & keywords
- Dysprosium
- Quantum tunnelling
- Magnet
- Dilution
- Magnetic relaxation
- Hysteresis
- Relaxation (psychology)
- Quantum