Response of an aerosol mass spectrometer to organonitrates and organosulfates and implications for atmospheric chemistry

Organonitrates (ON) are important products of gas-phase oxidation of volatile organic compounds in the troposphere; some models predict, and laboratory studies show, the formation of large, multifunctional ON with vapor pressures low enough to partition to the particle phase. Organosulfates (OS) have also been recently detected in secondary organic aerosol. Despite their potential importance, ON and OS remain a nearly unexplored aspect of atmospheric chemistry because few studies have quantified particulate ON or OS in ambient air. We report the response of a high-resolution time-of-flight aerosol mass spectrometer (AMS) to aerosol ON and OS standards and mixtures. We quantify the potentially substantial…

• NS
  National Science Foundation
• UD
  U.S. Department of Energy
• BY
  Brigham Young University
• UO
  University of Pittsburgh
• NO
  National Oceanic and Atmospheric Administration
• BA
  Biological and Environmental Research