Mechanical properties of hybrid inorganic–organic framework materials: establishing fundamental structure–property relationships

The mechanical properties of hybrid framework materials, including both nanoporous metal-organic frameworks (MOFs) and dense inorganic-organic frameworks, are discussed in this critical review. Although there are relatively few studies of this kind in the literature, major recent advances in this area are beginning to shed light on the fundamental structure-mechanical property relationships. Indeed research into the mechanical behavior of this important new class of solid-state materials is central to the design and optimal performance of a multitude of technological applications envisaged. In this review, we examine the elasticity of hybrid frameworks by considering their Young's modulus, Poisson's ratio,…