In situ high pressure study of ZIF-8 by FTIR spectroscopy
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Abstract
ZIF-8 as a promising storage material was investigated at high pressures up to ~39 GPa by in situ FTIR spectroscopy for the first time. Structural modifications are found to be reversible in a low-pressure region but irreversible in a high-pressure region. Overall, the ZIF-8 framework exhibits an unusual chemical stability even under extreme compression.
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Keywords
- Fourier transform infrared spectroscopy
- High pressure
- In situ
- Spectroscopy
- Materials science
- Compression (physics)
- Chemical engineering
- Chemistry
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