Magnetoelectric Polarizability and Axion Electrodynamics in Crystalline Insulators

The orbital motion of electrons in a three-dimensional solid can generate a pseudoscalar magnetoelectric coupling $\ensuremath{\theta}$, a fact we derive for the single-particle case using a recent theory of polarization in weakly inhomogeneous materials. This polarizability $\ensuremath{\theta}$ is the same parameter that appears in the ``axion electrodynamics'' Lagrangian $\ensuremath{\Delta}{\mathcal{L}}_{EM}=(\ensuremath{\theta}{e}^{2}/2\ensuremath{\pi}h)\mathbf{E}\ifmmode\cdot\else\textperiodcentered\fi{}\mathbf{B}$, which is known to describe the unusual magnetoelectric properties of the three-dimensional topological insulator ($\ensuremath{\theta}=\ensuremath{\pi}$). We compute $\ensuremath{\theta}$ for…