articleAngewandte Chemie International EditionSep 7, 2015Closed access

Highly Efficient Near‐Infrared Delayed Fluorescence Organic Light Emitting Diodes Using a Phenanthrene‐Based Charge‐Transfer Compound

Jilin University · State Key Laboratory of Supramolecular Structure and Materials

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Abstract

Significant efforts have been made to develop high-efficiency organic light-emitting diodes (OLEDs) employing thermally activated delayed fluorescence (TADF) emitters with blue, green, yellow, and orange-red colors. However, efficient TADF materials with colors ranging from red, to deep-red, to near-infrared (NIR) have been rarely reported owing to the difficulty in molecular design. Herein, we report the first NIR TADF molecule TPA-DCPP (TPA=triphenylamine; DCPP=2,3-dicyanopyrazino phenanthrene) which has a small singlet-triplet splitting (ΔEST ) of 0.13 eV. Its nondoped OLED device exhibits a maximum external quantum efficiency (EQE) of 2.1 % with a Commission International de L'Éclairage (CIE) coordinate of…

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