articleChemical CommunicationsJan 1, 2004Closed access

Ligand-free Heck reactions using low Pd-loading

MTManfred T. ReetzJGJohannes G. de Vries

Max Planck Society · Max-Planck-Institut für Kohlenforschung · +1 more institution

PubMed
Indexed incrossrefpubmed

Abstract

Activated and non-activated aryl bromides undergo smooth ligand-less Heck reactions, provided low amounts of palladium salts such as Pd(OAc)2 are used (ideally 0.01-0.1 mol%). This industrially viable process appears to involve palladium nanoparticles.

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Topics & keywords

Topics
Keywords
  • Palladium
  • Ligand (biochemistry)
  • Heck reaction
  • Aryl
  • Chemistry
  • Combinatorial chemistry
  • Catalysis
  • Organic chemistry
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