articleThe Journal of Chemical PhysicsSep 11, 2009GREEN OA

Highly efficient energy excitation transfer in light-harvesting complexes: The fundamental role of noise-assisted transport

London Institute for Mathematical Sciences · Imperial College London · +2 more institutions

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Abstract

Excitation transfer through interacting systems plays an important role in many areas of physics, chemistry, and biology. The uncontrollable interaction of the transmission network with a noisy environment is usually assumed to deteriorate its transport capacity, especially so when the system is fundamentally quantum mechanical. Here we identify key mechanisms through which noise such as dephasing, perhaps counter intuitively, may actually aid transport through a dissipative network by opening up additional pathways for excitation transfer. We show that these are processes that lead to the inhibition of destructive interference and exploitation of line broadening effects. We illustrate how these mechanisms…

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