Synthesis, Structure, and Electrochemical Behavior of Li[Ni[sub x]Li[sub 1/3−2x/3]Mn[sub 2/3−x/3]]O[sub 2]

Lu, Zhonghua; Beaulieu, Luc; Donaberger, R. A.; Thomas, Chunpen; Dahn, J. R.

doi:10.1149/1.1471541

articleJournal of The Electrochemical SocietyJan 1, 2002Closed access

Synthesis, Structure, and Electrochemical Behavior of Li[Ni[sub x]Li[sub 1/3−2x/3]Mn[sub 2/3−x/3]]O[sub 2]

ZLZhonghua Lu LBLuc Beaulieu RAR. A. Donaberger CTChunpen Thomas JRJ. R. Dahn

Steacie Institute for Molecular Sciences · Dalhousie University

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Abstract

The synthesis, structure, and electrochemical performance of for is presented. is prepared by substituting for and in while maintaining all the remaining Mn in the +4 oxidation state. Samples with 1/4, 1/3, 5/12, and 1/2 have been investigated by X-ray diffraction (XRD) and neutron diffraction as well as by electrochemical measurements. The XRD and neutron diffraction patterns of (0

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Topics & keywords

Topics

Keywords

Neutron diffraction
Electrochemistry
Lithium (medication)
Spinel
Diffraction
Materials science
Crystallography
X-ray crystallography

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