articleACS NanoMay 19, 2011Closed access

Electron Mobility and Injection Dynamics in Mesoporous ZnO, SnO 2 , and TiO 2 Films Used in Dye-Sensitized Solar Cells

University of Oxford

PubMed
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Abstract

High-performance dye-sensitized solar cells are usually fabricated using nanostructured TiO(2) as a thin-film electron-collecting material. However, alternative metal-oxides are currently being explored that may offer advantages through ease of processing, higher electron mobility, or interface band energetics. We present here a comparative study of electron mobility and injection dynamics in thin films of TiO(2), ZnO, and SnO(2) nanoparticles sensitized with Z907 ruthenium dye. Using time-resolved terahertz photoconductivity measurements, we show that, for ZnO and SnO(2) nanoporous films, electron injection from the sensitizer has substantial slow components lasting over tens to hundreds of picoseconds, while…

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782
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100%
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Authors

5

Topics & keywords

Keywords
  • Materials science
  • Nanoporous
  • Dye-sensitized solar cell
  • Electron mobility
  • Photocurrent
  • Thin film
  • Optoelectronics
  • Photoconductivity
UN Sustainable Development Goals
  • Affordable and clean energy
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