Electron Mobility and Injection Dynamics in Mesoporous ZnO, SnO 2 , and TiO 2 Films Used in Dye-Sensitized Solar Cells
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Abstract
High-performance dye-sensitized solar cells are usually fabricated using nanostructured TiO(2) as a thin-film electron-collecting material. However, alternative metal-oxides are currently being explored that may offer advantages through ease of processing, higher electron mobility, or interface band energetics. We present here a comparative study of electron mobility and injection dynamics in thin films of TiO(2), ZnO, and SnO(2) nanoparticles sensitized with Z907 ruthenium dye. Using time-resolved terahertz photoconductivity measurements, we show that, for ZnO and SnO(2) nanoporous films, electron injection from the sensitizer has substantial slow components lasting over tens to hundreds of picoseconds, while…
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782
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- 100%
- References
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Authors
5Topics & keywords
Topics
Keywords
- Materials science
- Nanoporous
- Dye-sensitized solar cell
- Electron mobility
- Photocurrent
- Thin film
- Optoelectronics
- Photoconductivity
UN Sustainable Development Goals
- Affordable and clean energy
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