reviewChemical Society ReviewsJan 1, 2015HYBRID OA

Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO 2 capture?

Delft University of Technology · Universidad de Zaragoza · +7 more institutions

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Abstract

The field of metal-organic framework based mixed matrix membranes (M(4)s) is critically reviewed, with special emphasis on their application in CO2 capture during energy generation. After introducing the most relevant parameters affecting membrane performance, we define targets in terms of selectivity and productivity based on existing literature on process design for pre- and post-combustion CO2 capture. Subsequently, the state of the art in M(4)s is reviewed against these targets. Because final application of these membranes will only be possible if thin separation layers can be produced, the latest advances in the manufacture of M(4) hollow fibers are discussed. Finally, the recent efforts in understanding…

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