articleJournal of the American Chemical SocietyJan 26, 2012Closed access

Water Oxidation Electrocatalyzed by an Efficient Mn 3 O 4 /CoSe 2 Nanocomposite

University of Science and Technology of China · National Synchrotron Radiation Laboratory

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Abstract

The design of efficient, cheap, and abundant oxygen evolution reaction (OER) catalysts is crucial to the development of sustainable energy sources for powering fuel cells. We describe here a novel Mn(3)O(4)/CoSe(2) hybrid which could be a promising candidate for such electrocatalysts. Possibly due to the synergetic chemical coupling effects between Mn(3)O(4) and CoSe(2), the constructed hybrid displayed superior OER catalytic performance relative to its parent CoSe(2)/DETA nanobelts. Notably, such earth-abundant cobalt (Co)-based catalyst afforded a current density of 10 mA cm(-2) at a small overpotential of ~0.45 V and a small Tafel slope down to 49 mV/decade, comparable to the best performance of the…

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