Experimental and Calculated Electrochemical Potentials of Common Organic Molecules for Applications to Single-Electron Redox Chemistry
University of North Carolina at Chapel Hill
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Abstract
Herein, we report half-peak potentials for over 180 organic substrates obtained via cyclic voltammetry. These values are of great use in assessing the thermodynamics of an electron-transfer process. In addition, we disclose a simple computational method to determine redox potentials of organic substrates.
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3Topics & keywords
Topics
Keywords
- Chemistry
- Redox
- Cyclic voltammetry
- Electrochemistry
- Electron transfer
- Computational chemistry
- Voltammetry
- Organic molecules
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