articleChemistry of MaterialsJul 8, 2015Closed access

Effect of Postetch Annealing Gas Composition on the Structural and Electrochemical Properties of Ti 2 CT x MXene Electrodes for Supercapacitor Applications

King Abdullah University of Science and Technology

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Abstract

Two-dimensional Ti2CTx MXene nanosheets were prepared by the selective etching of Al layer from Ti2AlC MAX phase using HF treatment. The MXene sheets retained the hexagonal symmetry of the parent Ti2AlC MAX phase. Effect of the postetch annealing ambient (Ar, N2, N2/H2, and air) on the structure and electrochemical properties of the MXene nanosheets was investigated in detail. After annealing in air, the MXene sheets exhibited variations in structure, morphology, and electrochemical properties as compared to HF treated MAX phase. In contrast, samples annealed in Ar, N2, and N2/H2 ambient retained their original morphology. However, a significant improvement in the supercapacitor performance is observed upon…

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