reviewChemical Society ReviewsJan 1, 2016Closed access

Recent advances in enantioselective gold catalysis

Berkeley College · University of California System · +1 more institution

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Abstract

Interest in homogeneous gold catalysis has undergone a marked increase. As strong yet air- and moisture-tolerant π-acids, cationic gold(i) complexes have been shown to catalyze diverse transformations of alkenes, alkynes and allenes, opening new opportunities for chemical synthesis. The development of efficient asymmetric variants is required in order to take full advantage of the preparative potential of these transformations. During the last few years, the chemical community has achieved tremendous success in the area. This review highlights the updated progress (2011-2015) in enantioselective gold catalysis. The discussion is classified according to the π-bonds activated by gold(i), in an order of alkynes,…

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