articleACS CatalysisMay 4, 2015Closed access

Cobalt Sulfide Nanoparticles Grown on Nitrogen and Sulfur Codoped Graphene Oxide: An Efficient Electrocatalyst for Oxygen Reduction and Evolution Reactions

Daegu Gyeongbuk Institute of Science and Technology

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Abstract

Electrochemical oxygen evolution and reduction reactions have received great attention due to their importance in several key technologies such as fuel cells, electrolyzers, and metal–air batteries. Here, we present a simple approach to the preparation of cobalt sulfide nanoparticles in situ grown on a nitrogen and sulfur codoped graphene oxide surface. The particle size and phase were controlled by changing the treatment temperature. Cobalt sulfide nanoparticles dispersed on graphene oxide hybrids were successfully prepared by a solid-state thermolysis approach at different temperatures (400, 500, and 600 °C) using cobalt thiourea and graphene oxide. X-ray diffraction studies revealed that hybrids prepared at…

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